INTRODUCTION
5-Methyl-3-vinyl-2-oxazolidinone (V-MOX) is a highly reactive monomer valued for its low viscosity, mild odor, and excellent reactivity. It is widely used as a reactive diluent in UV-curable inks and coatings, where it enhances adhesion, produces brighter colors, and improves safety compared to conventional diluents. In addition, V-MOX serves as a key building block in the synthesis of kinetic hydrate inhibitor (KHI) polymers, which are applied in oil and gas production to prevent hydrate blockages in pipelines.
Manufacture
V-MOX can be synthesized via a two-step process. In the first step, Cu(II)-catalyzed cyclization of (±)-1-amino-2-propanol with carbon monoxide under an oxygen atmosphere affords 5-methyl-2-oxazolidinone. This intermediate then undergoes ruthenium-catalyzed vinylation with acetylene to give V-MOX in good yields. Alternatively, V-MOX can also be obtained through pyrolysis of 3-(1-hydroxyethyl)-5-methyloxazolidin-2-one.
| Synonyms | N-Vinyl-5-methyl-2-oxazolidinone/ V-MOX |
| CAS no. | 3395-98-0 |
| EINECS no. | 809-852-5 |
| Molecular formula | C6H9NO2 |
| Molecular weight | 127.14 |
| Structure |  |
Applications
V-MOX is a versatile chemical intermediate and functional monomer, primarily used in specialty polymers and coating. The main areas of application include:
| Printing Inks & 3D Printing: |
| V-MOX acts as a reactive diluent in UV-curable inks and coatings, where it enhances adhesion to difficult substrates (plastics, metals, glass), and Improves gloss, scratch resistance, and weatherability. |
| UV Curing: |
| As a reactive diluent, VMOX reduces the viscosity of formulations and participates in the UV curing process itself, leading to polymers with good adhesion, durability, and vivid colors. |
| Oil & Gas Industry: |
| Serves as a building block for kinetic hydrate inhibitor (KHI) polymers, preventing gas hydrate blockages in subsea pipelines. Offers improved stability and efficiency in flow assurance applications. |
| Materials Science: |
| It serves as a building block for creating new polymers and materials with specific mechanical and chemical properties, including potential use in biomedical applications. |
| Coatings & Surface Modification: |
| Imparts durability and chemical resistance when incorporated into coating formulations. Supports development of thin, uniform, and crosslinked films. |
| Adhesives & Sealants: |
| Contributes to strong bonding and fast curing under UV or electron-beam radiation. Especially valuable in electronics assembly and packaging. |
SPECIFICATIONS
| Test | Unit | Specification |
|---|---|---|
| Appearance | – | Nearly colourless liquid |
| NMR -H | – | Should correspond to the structure |
| Purity (By HPLC) | % Area | Min 98.0 |
STORAGE & PRECAUTION
Keep sealed at room temperature, protected from light
PACKING
Compliant with international regulations
REACH Status
Not registered
ExSyn offers 5-Methyl-3-vinyl-2-oxazolidinone on commercial scales and welcomes enquiries. ExSyn has a capacity to supply this chemical over 1000MT annually. Our exceptional quality and service will make ExSyn your supplier of choice! If you need any additional information or SDS, please contact us.
Glycolaldehyde dimer is the cyclic dimeric form of glycolaldehyde, the simplest hydroxyaldehyde. Glycolaldehyde is often supplied as stable dimeric solid, commonly identified as 2,5-dihydroxy-1,4-dioxane.
N,N-Diisopropylethylamine (DIPEA), also known as Hünig’s Base, is a sterically hindered tertiary amine. It is a colorless liquid with a strong amine odor and is widely used as a low nucleophilic organic base in pharmaceutical, agrochemical, and fine chemical synthesis. Due to its bulky structure, DIPEA effectively scavenges acids without participating in unwanted side reactions.
Tris(2,4-di-tert-butylphenyl) phosphite (TDPP) often recognized commercially as Irgafos 168 is a high-performance organophosphorus compound primarily utilized as secondary antioxidant and processing stabilizer. Its characteristic to undergo metallation reaction and provide a cost-effective synthetic processes allows it to be useful in biaryl coupling reactions.
Undecylenic acid is an unsaturated fatty acid naturally derived from castor oil. It is a colorless to pale yellow liquid with antifungal and antimicrobial properties. Chemically known as 10-undecenoic acid, it contains an 11-carbon chain with one double bond and is widely used in pharmaceuticals
5-Nitro Isophthalic Acid (5-NIPA) is an aromatic organic compound derived from isophthalic acid. The presence of two carboxylic acid groups along with a nitro substituent at the 5-position makes it a valuable intermediate in the manufacture of fine chemicals, pharmaceuticals, dyes, pigments, and advanced materials.
Trichloroacetonitrile is a halogenated organic compound belonging to nitrile family. Its strong electrophilic character makes it a valuable intermediate in organic synthesis. It readily undergoes hydrolysis, particularly under acidic or basic conditions, yielding trichloroacetamide and related derivatives.
Zinc Dialkyl Dithio Phosphate (ZDDP) belongs to a family of coordination compounds classified as members of transition metal dithiophosphate.
ZDDP is widely used based on a combination of different selected alcohols thus providing antiwear performance and enhanced thermal and hydrolytic stability. In combination with other additives, it is especially used for the formulation of hydraulic fluids, industrial gear oils, metalworking fluids, greases and automotive engine oils.
Dibutyl sulfide is an organosulfur. It is a clear, colorless to pale yellow liquid characterized by a strong sulfur-like odor and is primarily used as an intermediate in chemical synthesis, specialty organic manufacturing, and research applications. The compound exhibits good solvency properties and moderate thermal stability, making it useful in industrial and laboratory processes involving sulfur-containing organic compounds.
Oleylamine is a long-chain (C18) primary fatty amine derived from natural fatty acids, typically sourced from vegetable oils. It is produced from oleic acid through conversion of the carboxylic acid group (–COOH) into an amine group (–NH₂). With its optimal balance of hydrophobic chain length and reactive amine functionality it serves as a versatile and dependable building block for high-performance formulations.